Well, everything that is worn...
If it's pulled apart then it's best to measure everything. Usually the camshaft and crankshaft don't wear away as quickly as say the cylinders,piston rings,bearings (depends on usage of course) but it's good to have a service manual as that contains all the measurements.
Another thing to do is to change all the seals/gaskets (whether they're good or not, usually are worn by the time the engine needs a rebuild). Cylinder head gasket is compulsary to change if the cylinder head is removed.
To check the condition of the cylinder head the valves have to be taken out.